Ubuntu Security :: Getting A Users Password ?

I need to be able to capture a users password when they login. I am well aware of the security issues with this and I'm ok with this.

We run a call center and I am working on migrating from windows to Kubuntu for the callers. It's policy that all callers must report their password to me, so I already know of everyone's password. There has to be some variable/script that I can "hack" to get the password they typed in to the login screen.

What I'm trying to do is that when a user logs in in for the first time, their profile is automatically created and set up. Setting up network drives, email, pidgin (which the password is stored in plain text anyway, so forget about security on that one), web apps, etc.

Trying to find information on How to capture a users password and all have been responded with the usual lecture on why you shouldn't do this. So I've heard it all before and I know of the risks. Like I said, I already have the callers password on file. If I could capture it, I wouldn't have to manually setup each profile every time we get a new caller, which is often since turnover is quite high in call centers.