General :: Merging Logical Volume Groups - Initial Setup

I am very new to LVM, as well as not especially experienced at linux, and have some questions about how lvm works. A few months back I set up a server running FC10 and tried creating Logical Groups during the the initial setup. We've realized that we are not using all the available space on the physical drive, and I realized that for some reason (I'm thinking this might have been the default?), we initially created two Logical Groups (VolGroup00 and VolGroup01) and it appears two Logical volumes in each (LogVol00 and LogVol01). LogVol00 in VolGroup00 is mapped to /, and the other Group was actually unused. I figure that it would be simplest to just use all this space mapped to /, so I thought the thing to do would be to simply merge VolGroup01 to VolGroup00. I tried this:

[root@office mapper]# vgmerge VolGroup00 VolGroup01
Logical volumes in "VolGroup01" must be inactive

So after a bit of research, I tried this:

[root@office mapper]# vgchange -a n VolGroup01
Can't deactivate volume group "VolGroup01" with 1 open logical volume(s)

So apparently There's an open volume, but I don't know how to go about closing it. I removed the LogVol00 from that group, but LogVol01 won't budge.

[root@office mapper]# lvremove VolGroup01
Can't remove open logical volume "LogVol01"

So how do I go about closing this Volume? At one point, there was some output that told me LogVol01 was being used as swap space. How do I handle that?